Identification of tetramethylarsonium in rice grains with elevated arsenic content

Tetramethylarsonium has for the first time been identified in a commercially grown food product, rice, constituting up to 5.8% of the total arsenic in the rice.     

Changing the Course of Rivers in an Asian City: Linking Landscapes to Human Benefits through Iterative Modeling and Design

Concerns over water scarcity, climate change, and environmental health risks have prompted some Asian cities to invest in river rehabilitation, but deciding on the end goals of rehabilitation is a complex undertaking. We propose a multidisciplinary framework linking riparian landscape change to human well‐being, providing information relevant to decision makers, in a format that facilitates stakeholder involvement. We illustrate this through a case study of the densely settled, environmentally degraded, and flood prone Ciliwung River flowing through metropolitan Jakarta, Indonesia. Our methodology attempts to respond to this complexity through an iterative approach, strongly based on conceptualization and mathematical modeling. Nested hydrologic, hydrodynamic, and water quality models provide outputs at catchment‐, corridor‐, and localized site‐scales. Advanced 3‐D landscape modeling is used for procedural design and precise visualization of proposed changes and their impacts, as predicted by the mathematical models. Finally, participatory planning and design methods allow us to obtain critical stakeholder feedback in shaping a socially acceptable approach. Our framework aims at demonstrating that a change in paradigm in river rehabilitation is possible, and providing future scenarios that balance concerns over flooding, water quality, and ecology, with the realities of a rapidly growing megacity.     

The use of 'exotic' framework structures in waste management

The use of porous framework materials in waste management applications has the potential to be a powerful tool in toxic metal remediation. The properties that these materials possess, including high surface area and ion-exchange capacity, are theoretically valuable. Furthermore, the flexibility of many of these frameworks allows the potential for immobilisation of waste materials with the framework of the material, in addition to the traditional capture in the pore structure. However, for either of these routes to be useful for waste management purposes, these structures must also be stable in any proposed storage media. This study examines the stability of a range of porous materials whose frameworks are made out of zinc and arsenic, both considered toxic minesite wastes, when exposed to aqueous media. The three frameworks examined (sodalite analogue Na(6)(H(2)O)(8)(ZnAsO(4))(6), open framework K(3)Zn(4)O(AsO(4))(3).3.5H(2)O, and an ABW type framework NH(4)ZnAsO(4)) all have similar hydrothermal synthetic routes and bulk framework compositions, but differ in counter ion used, pore size and complexity of structure. The phases were examined before and after storage in an aqueous environment, and their crystallinity and leaching were determined. All phases prepared were found to be extremely unstable outside their original synthetic environment, and very soluble when exposed to water, calling into question their practical use in any environment.     

Survey of arsenic and its speciation in rice products such as breakfast cereals, rice crackers and Japanese rice condiments

Rice has been demonstrated to be one of the major contributors to arsenic (As) in human diets in addition to drinking water, but little is known about rice products as an additional source of As exposure. Rice products were analyzed for total As and a subset of samples were measured for arsenic speciation using high performance liquid chromatography interfaced with inductively coupled plasma-mass spectrometry (HPLC-ICP-MS). A wide range of rice products had total and inorganic arsenic levels that typified those found in rice grain including, crisped rice, puffed rice, rice crackers, rice noodles and a range of Japanese rice condiments as well as rice products targeted at the macrobiotic, vegan, lactose intolerant and gluten intolerance food market. Most As in rice products are inorganic As (75.2-90.1%). This study provides a wider appreciation of how inorganic arsenic derived from rice products enters the human diet.     

Material flow analysis of RDF-production processes

The authors evaluate the possibilities of modifying the chemical characteristics of refuse-derived fuels (RDF) that are processed from residual household waste by mechanical operations to achieve and assure quality targets for relevant chemical concentrations, especially for heavy metals and chlorine. Quality assurance in the production of RDF demands that, together with an enrichment of the calorific value, highly toxic waste components are selectively separated and concentrated in a small stream to produce high yields of a relatively low polluted fuel. Based on the method of material flow analysis, a process evaluation is developed that considers the aspect of minimizing hazardous chemicals along with classical process data such as yield and product quality. Data on specific concentration of hazardous chemicals in waste components and their distribution in residual household waste as well as the results from large-scale test runs using different separation techniques demonstrate that mechanical operations alone are insufficient for separating hazardous chemicals. In the test runs, chemical compounds such as chlorine, cadmium and lead were often concentrated in the product. Even using optimized techniques, the ability to reduce hazards in the product is limited due to the distribution of the element concentration in the various components of the waste stream.     

Two Pilot Plant Reactors Designed for the In Situ Bioremediation of Chlorobenzene-contaminated Ground Water: Hydrogeological and Chemical Characteristics and Bacterial Consortia

The SAFIRA in situ pilot plant in Bitterfeld, Saxonia-Anhalt, Germany, currently serves as the test site for eight different in situ approaches to remediate anoxic chlorobenzene (CB)-contaminated ground water. Two reactors, both filled with originallignite-containing aquifer material, are designed for themicrobiological in situ remediation of the ground water bythe indigenous microbial consortia. In this study, thehydrogeological, chemical and microbiological conditions of theinflowing ground water and reactor filling material are presented,in order to establish the scientific basis for the start of thebioremediation process itself. The reactors were put intooperation in June 1999. In the following, inflow CB concentrationsin the ground water varied between 22 and 33 mg L^-1; achemical steady state for CB in both reactors was reachedafter 210 till 260 days operation time. The sediments werecolonized by high numbers of aerobic, iron-reducing anddenitrifying bacteria, as determined after 244 and 285 days ofoperation time. Furthermore, aerobic CB-degrading bacteria weredetected in all reactor zones. Comparative sequence analysis of16S rDNA gene clone libraries suggest the dominance of Proteobacteria (Comamonadaceae, Alcaligenaceae, Gallionella group, Acidithiobacillus) and members of theclass of low G+C gram-positive bacteria in the reactorsediments. In the inflowing ground water, sequences withphylogenetic affiliation to sulfate-reducing bacteria andsequences not affiliated with the known phyla of Bacteria, were found.     

Online elemental analysis of process gases with ICP-OES: A case study on waste wood combustion

A mobile sampling and measurement system for the analysis of gaseous and liquid samples in the field was developed. An inductively coupled plasma optical emission spectrometer (ICP-OES), which is built into a van, was used as detector. The analytical system was calibrated with liquid and/or gaseous standards. It was shown that identical mass flows of either gaseous or liquid standards resulted in identical ICP-OES signal intensities. In a field measurement campaign trace and minor elements in the raw flue gas of a waste wood combustor were monitored. Sampling was performed with a highly transport efficient liquid quench system, which allowed to observe temporal variations in the elemental process gas composition. After a change in feedstock an immediate change of the element concentrations in the flue gas was detected. A comparison of the average element concentrations during the combustion of the two feedstocks showed a high reproducibility for matrix elements that are expected to be present in similar concentrations. On the other hand elements that showed strong differences in their concentration in the feedstock were also represented by a higher concentration in the flue gas. Following the temporal variations of different elements revealed strong correlations between a number of elements, such as chlorine with sodium, potassium and zinc, as well as arsenic with lead, and calcium with strontium.     

Human migration,climate variability,and land degradation: hotspots of socio-ecological pressure in Ethiopia

Regional Environmental Change - In Ethiopia, human migration is known to be influenced by environmental change—and vice versa. Thus, degradation of environmental conditions can contribute to...     

Inorganic arsenic levels in rice milk exceed EU and US drinking water standards

Under EU legislation, total arsenic levels in drinking water should not exceed 10 microg l(-1), while in the US this figure is set at 10 microg l(-1) inorganic arsenic. All rice milk samples analysed in a supermarket survey (n = 19) would fail the EU limit with up to 3 times this concentration recorded, while out of the subset that had arsenic species determined (n = 15), 80% had inorganic arsenic levels above 10 microg l(-1), with the remaining 3 samples approaching this value. It is a point for discussion whether rice milk is seen as a water substitute or as a food, there are no EU or US food standards highlighting the disparity between water and food regulations in this respect.